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    Cyanide is a lixiviant, or reagent that is used to leach, often in tanks, gold from a solid matrix and form a gold cyanide complex. The gold cyanide complex is then extracted from the pulp or slurry by adsorption onto activated carbon. CIL stands for carbon in leach. This is a gold extraction process called cyanidation where carbon is added to the leach tanks (or reaction vessel) so that leaching and adsorption take

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    The addition of cyanide produces a stable gold cyanide species, Au(CN)2 . Figure 7.4 shows the region where gold can be leached by a cyanide solution to form gold cyanide. Figure 7.3 Figure 7.4 From the gold cyanide Eh pH diagram it can be seen that gold will leach from a pH of 0 to 14. The lowest Eh value occurs at a pH of about 10.5.

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    High gold cyanide and cation concentrations, low temperatures, low anion concentrations and active carbon drive the gold cyanide onto the carbon. During elution, lack of cations (Ca2+, Mg2+, etc), high anion concentration (CN , OH ) and high temperatures will disrupt the equilibrium and remove gold cyanide from the carbon.

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    More importantly, gold in an ore may occur in two or three forms (i.e., microscopic gold, submicroscopic gold, and surface gold), making gold ore processing extremely challenging.

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